6-Meth­oxy-2-methyl-1-phenyl-1H-indole-3-carbonitrile

نویسندگان

  • Qiao Yan
  • Xiuxiang Qi
چکیده

In the title compound, C(17)H(14)N(2)O, the dihedral angle between the indole ring system and the phenyl ring is 64.48 (7)°. The crystal packing features weak C-H⋯π inter-actions.

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منابع مشابه

1-(4-Bromo­phen­yl)-2-methyl-1H-indole-3-carbonitrile

In the title compound, C(16)H(11)BrN(2), the dihedral angle between the indole ring system and the phenyl ring is 58.85 (11)°.

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6′-Amino-3′-methyl-2-oxo-1′-phenyl-1′,3a′,4′,7a′-tetra­hydrospiro­[1H-indole-3(2H),4′-pyrano[2,3-d]pyrazole]-5′-carbonitrile. Corrigendum

The title and chemical structural diagram in Etti, Shanmugam & Perumal [Acta Cryst. (2008), E64, o341] are corrected.[This corrects the article DOI: 10.1107/S1600536807064926.].

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Ethyl 2-[(N-meth­oxy-N-methyl­carbamo­yl)meth­yl]-1-(phenyl­sulfon­yl)-1H-indole-3-carboxyl­ate

In the title compound, C(21)H(22)N(2)O(6)S, the phenyl ring forms a dihedral angle of 83.17 (7)° with the indole ring system. The methyl group of the ester unit is disordered over two positions with site occupancies of 0.635 (6) and 0.365 (6). In the crystal structure, weak intra-molecular C-H⋯O inter-actions and inter-molecular C-H⋯O, C-H⋯N and C-H⋯π inter-actions are observed.

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Apart from the methyl group of the meth-oxy fragment, the title compound, C(15)H(12)N(2)O, is almost planar (r.m.s. deviation = 0.045 Å); the C atom deviates from the mean plane by 1.216 (1) Å. In the crystal, π-π stacking [shortest centroid-centroid separation = 3.4652 (10) Å] and C-H⋯π inter-actions occur.

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Diethyl 2-[(5-meth­oxy-2-methyl-1-phenyl­sulfonyl-1H-indol-3-yl)methyl­ene]malonate

In the title compound, C(24)H(25)NO(7)S, the sulfonyl-bound phenyl ring is approximately perpendicular to the indole ring system [dihedral angle = 87.72 (5)°]. The methyl group of one of the ester units is disordered over two positions with occupancies of 0.527 (13) and 0.473 (13). An intra-molecular C-H⋯O hydrogen bond is observed. In the crystal structure, mol-ecules are linked into a ribbon ...

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عنوان ژورنال:

دوره 67  شماره 

صفحات  -

تاریخ انتشار 2011